A popular one-day or half-day excursion is to the Sunday market at Tarabuco. Any tour agency can arrange a tour, or there are frequent vans and trucks on the road to and from Tarabuco. It takes about two hours to reach the town. It is important to leave early; the markets are at their best before lunch time, and begin to pack up in the early afternoon.
For a far less touristed experience visited Candelaria. This village is further from Sucre than Tarabuco, but a part of the same culture that is renowned nation-wide for its handicrafts. Prices are better than at Tarabuco. Transportation is very limited and people have been stuck out here, so it's best to go with a tour agency.
One of the most popular destinations outside of Sucre is Maragua crater, a region of unusual rock formations. The crater is not volcanic contrary to what some say, but was formed by erosion. Fossils of marine shells are still found in the region and sold by local children. It is possible to spend a night in the village inside the crater. Conditions are basic but the experience unique. Simple meals are available too.
There are many other popular destinations that most tour groups can arrange visits to. At Icla there are rubber-tubing tours through a river canyon. The village of Yamparaez, on the road to Tarabuco is a good starting point for condor-spotting treks. There were once natural thermal baths by the river behind Maragua, but an avalanche or ownership dispute that was settled by dynamite depends who you talk to, destroyed these. It is hoped they will be reconstructed soon.
If you are planning on doing much trekking or camping in the mountains around Sucre, it is highly recommended that you take a guide. Conditions change fast, many of the routes are small or hard to find, and it is important to be sensitive to local cultures also note the language of chocie is Quechua, so don't assume anyone you meet can speak Spanish. For these reasons it is very useful to have a local guide with you. For one or more-day expeditions to the Cordillera de los Frailes, the Dutch run Travel Agency "Bolivia Specialist" at Nicolás Ortiz #30 is highly recommended. After office hours they have a person for Tours at the Café Restaurant "FlorÃn" at the BolÃvar #567.
Condortrekkers arranges locally-lead trekking expeditions to most of the above destinations, and are currently the only organisation that offer overnight trips to Tarabuco, staying in a local village before hitting Tarabuco first thing in the morning. For more info see the listing above or visit Condortrekkers (http://www.condortrekkers.org/).
If you stay longer and want to escape the city for some fresh air and nature, consider the Centro Ecologico in Aritumayu, splendid clean river with waterfalls nearby, and basic but clean accomodation available romantic: no electricity nor cellphone coverage 1.5 hour drive by 4WD. Bookings via High Routes at Bolivar #482. (http://www.ecolodge-aritu...)